De Broglie proposed that electrons travel through space as a wave
This would explain why they can exhibit behaviour such as diffraction
He therefore suggested that electrons must also hold wave properties, such as wavelength
This came to be known as the de Broglie wavelength
However, he realised all particles can show wave-like properties, not just electrons
He hypothesised that all moving particles have a matter wave associated with them
This is known as the de Broglie wavelength, and can be defined as:
The wavelength associated with a moving particle
The majority of the time, and for everyday objects travelling at normal speeds, the de Broglie wavelength is far too small for any quantum effects to be observed
A typical electron in a metal has a de Broglie wavelength of about 10 nm
Therefore, quantum mechanical effects will only be observable when the width of the sample is around that value
The electron diffraction tube can be used to investigate how the wavelength of electrons depends on their speed
The smaller the radius of the rings, the smaller the de Broglie wavelength of the electrons
As the voltage is increased:
The energy of the electrons increases
The radius of the diffraction pattern decreases
This shows as the speed of the electrons increases, the de Broglie wavelength of the electrons decreases
Using ideas based upon the quantum theory and Einstein’s theory of relativity, de Broglie suggested that the momentum (p) of a particle and its associated wavelength (λ) are related by the equation:Kinetic Energy