When electrons pass through a slit similar in size to themselves, they exhibit a wavelike property( Diffraction), meaning they spread out like a wave passing through a narrow gap
The regular spacing of atoms in a crystalline solid act as a diffraction grating, scattering the electrons in a predictable manner
The observed diffraction pattern can be used to deduce the structure of the crystal producing that pattern
High energy electrons have a shorter wavelength and can therefore be used to look at the size of the nucleus of an atom as opposed to the arrangement of atoms in a crystal
The de Broglie wavelength tells us about the wave-particle relationship:
Where:
λ = the de Broglie wavelength (m)
h = Planck’s Constant (J s)
m = mass of the electron (kg)
v = velocity of the electron (m s–1)
Comparison of electron diffraction patterns at different values of momentum
Momentum
Momentum is equal to p = mv, so, from de Broglie's equation:
A smaller momentum will result in a longer wavelength
A larger momentum will result in a shorter wavelength
Kinetic Energy
If the electron speed / kinetic energy is increased, by increasing the accelerating voltage, then:
The wavelength of the wave will decrease
The diffraction rings will appear closer together
The higher the kinetic energy of the electron, the higher its momentum hence the smaller its wavelength
Radius of the Diffraction Pattern
The radius of the diffraction pattern depends on the wavelength:
The longer the wavelength, the more the light spreads out hence a larger radius is produced
The shorter the wavelength, the smaller the radius produced
Therefore, electrons with smaller momentum will produce a more diffuse diffraction pattern