AQA A Level Chemistry复习笔记5.2.4 The Arrhenius Equation

• The rate equation shows how each of the reactants in a reaction effects the rate of the reaction and it includes the rate constant, k
• However, k only remains constant if the concentration of the reactants is the only factor which is changed
  • If the temperature is changed or a catalyst is used or changed, then the rate constant, k, changes

   

• At higher temperatures, a greater proportion of molecules have energy greater than than the activation energy
• Since the rate constant and rate of reaction are directly proportional to the fraction of molecules with energy equal or greater than the activation energy, then at higher temperatures:
  • The rate of reaction increases
  • The rate constant increases

   

• The relationship between the rate constant, the temperature and also the activation energy is given by the following equation:

• A varies only a little bit with temperature; it can be considered a constant
• e, Ea and R are also constants

Using the Arrhenius Equation

• This equation is far easier to use if you take natural logarithms of each side of the equation, which results in the following equation:

• In the exam you could be asked to calculate any part of the Arrhenius Equation, and using it in this form will make it easier
• The Arrhenius Equation can be used to show the effect that a change in temperature has on the rate constant, k, and thus on the overall rate of the reaction
  • An increase in temperature (higher value of T) gives a greater value of ln k (and therefore a higher value of k)
  • Since the rate of the reaction depends on the rate constant (k) an increase in k also means an increased rate of reaction

   

• The equation can also be used to show the effect of increasing the activation energy on the value of the rate constant, k
  • An increase in the activation energy (Ea) means that the proportion of molecules which possess at least the activation energy is less
  • This means that the rate of the reaction, and therefore the value of k, will decrease

   

• The values of k and T can be used to calculate the activation energy for a reaction, which is the most common type of calculation you will be asked to do on this topic